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The total sum of squares, i.e. the left-hand side of Eq. (5.12.1), is clearly fixed oncethe experimental yi values have been determined. A line fitting these experimentalpoints closely will be obtained when the variation due to regression (the first term onthe right-hand side of Eq. (5.12.1) is as large as possible. The variation about regression(also called the residual SS as each component of the right-hand term in theequation is a single residual) should be as small as possible. The method is quite generaland can be applied to straight line regression problems as well as to curvilinearregression. Table 5.1 (see p. 133) shows the Excel® output for a linear plot used to comparetwo analytical methods, including an ANOVA table set out in the usual way. Thetotal number of degrees of freedom (19 in that example) is, as usual, one less than thenumber of measurements (20), as the y-residuals always add up to zero. For a straightline graph we have to determine only one coefficient (b) for a term that also contains x,so the number of degrees of freedom due to regression is 1. Thus there are (n 2)18degrees of freedom for the residual variation. The mean square (MS) values are determinedas in previous ANOVA examples, and the F-test is applied to the two meansquares as usual. The F-value obtained is very large, as there is an obvious relationshipbetween x and y, so the regression MS is much larger than the residual MS.
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