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Bahasa Indonesia) 1:
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The metallic bond has had a very spotty history inthe chemical literature. Whereas the thrust of bandtheory has been the prediction and rationalization ofthe thermal, electrical, and magnetic properties of metals,chemists are far more interested in bonding modelswhich offer simple correlations between valenceelectroncounts and both the compositions and structuresof possible compounds. Though they have beenvery successful in developing such correlations in thecases of both the covalent and ionic bonding extremes,similar success in the case of intermetallic compoundsand alloys has been almost totally lacking. While onecan cite the pioneering attempts of such metallurgistsas Hume-Rothery, Laves, and Engels, as well as thebrilliant work of the German chemist, Eduard Zintl, onthe transition between ionic and metallic bonding, thesituation today remains much the same as when it wassummarized by Fernelius and Robey in 1935 (9):The classification of intermetallic compounds is verydifficult. Not only are the experimental difficultiesgreat, but as yet no single theoretical or empiricalmethod of treatment has been sufficiently powerful toelucidate more than a portion of the entire field.
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