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Polymorphism is the ability of a molecule to take more than one crystalline form depending on its arrangement within the crystal lattice.
differences in hydrocarbon chain packing and variations in the angle of tilt of the hydrocarbon chain packing differentiate polymorphic forms.
The crystallization behavior of TAG: crystallization rate, crystal size, morphology, and total crystallinity, are affected by polymorphism.
The molecular structure of the TAG and several external factors like temperature, pressure, rate of crystallization, impurities, and shear rate influence polymorphism.
The rate of polymorphic transformation depends on the length of the fatty acid chain and is the greatest for TAGs with short-chain fatty acids.
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