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[Salinan]Disalin!
The formation of new nuclei in the presence of existing crystals is called secondary nucleation.
may occur whenever microscopic crystalline elements are separated from an existing crystal surface,
Contact secondary nucleation is probably the main mechanism in commercial fat crystallization processes.
As a crystal slurry is agitated in a vessel, crystals contacting with other crystals, vessel walls, or stirrer may lead to attrition or fracture of the existing crystal structure, and consequently, secondary nuclei are formed .
Contact secondary nucleation has been explained by two possible mechanisms, namely, the adsorption layer theory and microattrition.
The adsorption layer theory involves displacement of a surface layer of organized molecules (precrystalline) as a result of crystal interactions or collisions.
Thus, precrystalline embryos are dispersed into the crystallizing medium, where under conditions of secondary nucleation they survive and develop into stable nuclei.
Microattrition theory involves the dispersion of broken pieces of a crystal into the fluid, which remain as stable nuclei.
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